Deputies spotted Peter Nash, 24, and Jinny Angels, 20, both of Lake Elsinore, driving a stolen Honda and took them into custody.
Police say the pair broke into the victim's car in Dana Point and got her address off her vehicle registration.
They allegedly stole about $10,000 worth of property, as well as the homeowner's gun.
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The pair was recorded on the homeowner's security camera.
At one point, the woman, who police say is Angels, spots the camera and calls over her accomplice, allegedly Nash.
"There's a camera," the woman can be heard saying.
Detectives are now trying to determine if the suspects are connected to any other burglaries.